Organocatalytic Approach in Asymmetric Piancatelli Reactions: An Update
Dr. Sushovan Paladhi
, Dr. Bablu Kumar , Dr. Barnali Jana
Asymmetric organocatalysis, Piancatelli reactions, rearrangement reaction, 2-furylcarbinol
In the Piancatelli reaction, 2-furylcarbinol is converted into functionalized cyclopentenone via an intermediate called furanoxonium and consequent ring opening followed by an electrocyclization reaction of 4 electron system, was first discovered by Piancatelli in 1976. As a result of this work, important molecular scaffolds have been obtained, which are not only present in a number of natural products, but they are also used to synthesize a variety of bioactive compounds, including prostaglandins, sibirinones, and verrillins naturally found in nature. Several chiral chiral Brønsted acid based on BINOL derived chiral phosphoric acids or pentacarboxycyclopentadiene (PCCP) were utilized for the asymmetric Piancatelli reactions. Here, the complete developments on the asymmetric oganocatalytic methods will be discussed till date.
"Organocatalytic Approach in Asymmetric Piancatelli Reactions: An Update", IJSDR - International Journal of Scientific Development and Research (www.IJSDR.org), ISSN:2455-2631, Vol.9, Issue 5, page no.325 - 329, May-2024, Available :https://ijsdr.org/papers/IJSDR2405046.pdf
Volume 9
Issue 5,
May-2024
Pages : 325 - 329
Paper Reg. ID: IJSDR_211296
Published Paper Id: IJSDR2405046
Downloads: 000347294
Research Area: Chemistry
Country: Patna, Bihar, India
DOI: https://doi.org/10.5281/zenodo.11213721
ISSN: 2455-2631 | IMPACT FACTOR: 9.15 Calculated By Google Scholar | ESTD YEAR: 2016
An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 9.15 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator
Publisher: IJSDR(IJ Publication) Janvi Wave
