INTERNATIONAL JOURNAL OF SCIENTIFIC DEVELOPMENT AND RESEARCH International Peer Reviewed & Refereed Journals, Open Access Journal ISSN Approved Journal No: 2455-2631 | Impact factor: 8.15 | ESTD Year: 2016
open access , Peer-reviewed, and Refereed Journals, Impact factor 8.15
Isoquinolinium chlorochromate mediated oxidation of some diols - A Kinetic Study
Authors Name:
Ranjana Tripathi
, O.P. Rai
Unique Id:
IJSDR2307130
Published In:
Volume 8 Issue 7, July-2023
Abstract:
The oxidation kinetics of two diols (1,3-propane diol and 1,4-butane diol) by isoquinolinium chlorochromate in aqueous acetic acid medium in presence of mineral acid yielded in the formation of corresponding aldehydes as the main product of the oxidation. The reactions exhibit of first-order with respect to [IQCC], however showing fractional-order kinetic with respect to diols and kobs= a+b [H+] traits for [H+]. The study reveals the existence of symmetrical nature of transition state in the rate-determining step. The solvent effect shows the importance of the cation solvating power. A protonated species of oxidant participate in 1:1 stoichiometry ratio based proposed mechanism involving the proton abstracting mechanism supported by thermodynamic parameters.
"Isoquinolinium chlorochromate mediated oxidation of some diols - A Kinetic Study", International Journal of Science & Engineering Development Research (www.ijsdr.org), ISSN:2455-2631, Vol.8, Issue 7, page no.872 - 875, July-2023, Available :http://www.ijsdr.org/papers/IJSDR2307130.pdf
Downloads:
000338536
Publication Details:
Published Paper ID: IJSDR2307130
Registration ID:207891
Published In: Volume 8 Issue 7, July-2023
DOI (Digital Object Identifier):
Page No: 872 - 875
Publisher: IJSDR | www.ijsdr.org
ISSN Number: 2455-2631
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