Isoquinolinium chlorochromate mediated oxidation of some diols - A Kinetic Study
Ranjana Tripathi
, O.P. Rai
Isoquinolinium chlorochromate, 1,3-propane diol, 1,4-butane diol, oxidation, kinetics.
The oxidation kinetics of two diols (1,3-propane diol and 1,4-butane diol) by isoquinolinium chlorochromate in aqueous acetic acid medium in presence of mineral acid yielded in the formation of corresponding aldehydes as the main product of the oxidation. The reactions exhibit of first-order with respect to [IQCC], however showing fractional-order kinetic with respect to diols and kobs= a+b [H+] traits for [H+]. The study reveals the existence of symmetrical nature of transition state in the rate-determining step. The solvent effect shows the importance of the cation solvating power. A protonated species of oxidant participate in 1:1 stoichiometry ratio based proposed mechanism involving the proton abstracting mechanism supported by thermodynamic parameters.
"Isoquinolinium chlorochromate mediated oxidation of some diols - A Kinetic Study", IJSDR - International Journal of Scientific Development and Research (www.IJSDR.org), ISSN:2455-2631, Vol.8, Issue 7, page no.872 - 875, July-2023, Available :https://ijsdr.org/papers/IJSDR2307130.pdf
Volume 8
Issue 7,
July-2023
Pages : 872 - 875
Paper Reg. ID: IJSDR_207891
Published Paper Id: IJSDR2307130
Downloads: 000347153
Research Area: Engineering
Country: -, -, India
ISSN: 2455-2631 | IMPACT FACTOR: 9.15 Calculated By Google Scholar | ESTD YEAR: 2016
An International Scholarly Open Access Journal, Peer-Reviewed, Refereed Journal Impact Factor 9.15 Calculate by Google Scholar and Semantic Scholar | AI-Powered Research Tool, Multidisciplinary, Monthly, Multilanguage Journal Indexing in All Major Database & Metadata, Citation Generator
Publisher: IJSDR(IJ Publication) Janvi Wave
