INTERNATIONAL JOURNAL OF SCIENTIFIC DEVELOPMENT AND RESEARCH International Peer Reviewed & Refereed Journals, Open Access Journal ISSN Approved Journal No: 2455-2631 | Impact factor: 8.15 | ESTD Year: 2016
open access , Peer-reviewed, and Refereed Journals, Impact factor 8.15
Oxidation of Some Aldoses by N-Chlorophthalimide in Aqueous Acetic Acid Medium - A Kinetic Study
Authors Name:
Surabhi Dwivedi
, H.D. Gupta
Unique Id:
IJSDR2302149
Published In:
Volume 8 Issue 2, February-2023
Abstract:
D-glucose and D-ribose oxidation by N-chlorophthalimide has been examined in aqueous acetic acid medium. The main product of the oxidation is the corresponding aldonic acid. The reaction is first-order in [NCP]. Michaelis-Menten type kinetics have been observed with respect to the aldoses and independent in the ionic strength of the solution. The temperature dependence of kinetics i.e. negative entropy of activation revealed the presence of symmetrical transition state in the rate determining disproportionation step. The acid dependent and independent paths of [H+] was explained. A suitable mechanism in consistence with the kinetic results has been proposed.
"Oxidation of Some Aldoses by N-Chlorophthalimide in Aqueous Acetic Acid Medium - A Kinetic Study", International Journal of Science & Engineering Development Research (www.ijsdr.org), ISSN:2455-2631, Vol.8, Issue 2, page no.870 - 874, February-2023, Available :http://www.ijsdr.org/papers/IJSDR2302149.pdf
Downloads:
000337075
Publication Details:
Published Paper ID: IJSDR2302149
Registration ID:204232
Published In: Volume 8 Issue 2, February-2023
DOI (Digital Object Identifier):
Page No: 870 - 874
Publisher: IJSDR | www.ijsdr.org
ISSN Number: 2455-2631
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