INTERNATIONAL JOURNAL OF SCIENTIFIC DEVELOPMENT AND RESEARCH International Peer Reviewed & Refereed Journals, Open Access Journal ISSN Approved Journal No: 2455-2631 | Impact factor: 8.15 | ESTD Year: 2016
open access , Peer-reviewed, and Refereed Journals, Impact factor 8.15
Here we describe the kinetics of ethyl acetoacetate oxidation mediated by Quinolinium dichromate in aqueous acetic acid and mineral acid medium which yields to the formation of α,β-diketo butyric acid. The uncatalyzed reaction was shown to proceed by complex mechanism involving a pre-equilibrium of its adducts. The reaction is first-order in [QDC] that follows protonated and non-protonated dependency showing occurrence of α-C-H cleavage. The activation parameters have also been determined, which could be applied to explain all experimental phenomenon.
"Oxidation of Ester by Quinolinium Dichromate", International Journal of Science & Engineering Development Research (www.ijsdr.org), ISSN:2455-2631, Vol.8, Issue 1, page no.1224 - 1227, January-2023, Available :http://www.ijsdr.org/papers/IJSDR2301195.pdf
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Publication Details:
Published Paper ID: IJSDR2301195
Registration ID:203769
Published In: Volume 8 Issue 1, January-2023
DOI (Digital Object Identifier):
Page No: 1224 - 1227
Publisher: IJSDR | www.ijsdr.org
ISSN Number: 2455-2631
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