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INTERNATIONAL JOURNAL OF SCIENTIFIC DEVELOPMENT AND RESEARCH International Peer Reviewed & Refereed Journals, Open Access Journal ISSN Approved Journal No: 2455-2631 | Impact factor: 8.15 | ESTD Year: 2016 open access , Peer-reviewed, and Refereed Journals, Impact factor 8.15 |
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| Paper Title: | 1,3-Dichloro-5,5-Dimethylhydantoin mediated oxidation of unsaturated alcohols in aqueous acetic acid medium |
| Authors Name: | Divakar Prasad Sharma , Saras Tiwari |
| Unique Id: | IJSDR2307132 |
| Published In: | Volume 8 Issue 7, July-2023 |
| Abstract: | In this perspective, the use of redox process are addressed in kinetic study of unsaturated alcohols (α-crotyl and cinnamyl alcohols) by DCDMH. Kinetic evidence for the formation of a DCDMH– unsaturated alcohol 1:1 complex has been assigned. The rate-limiting step involves the breaking of the α-C-H bond to afford corresponding aldehydes in good yields, and oxidizing ability of DCDMH species have been discussed. Mechanism with the associated reaction kinetics is assigned in accordance with the rate law and kinetic parameters. |
| Keywords: | 1,3-dichloro-5,5-dimethylhydantoin, α-crotonic acid, cinnamic acid, oxidation, kinetics. |
| Cite Article: | "1,3-Dichloro-5,5-Dimethylhydantoin mediated oxidation of unsaturated alcohols in aqueous acetic acid medium", International Journal of Science & Engineering Development Research (www.ijsdr.org), ISSN:2455-2631, Vol.8, Issue 7, page no.881 - 885, July-2023, Available :http://www.ijsdr.org/papers/IJSDR2307132.pdf |
| Downloads: | 000338536 |
| Publication Details: | Published Paper ID: IJSDR2307132 Registration ID:207906 Published In: Volume 8 Issue 7, July-2023 DOI (Digital Object Identifier): Page No: 881 - 885 Publisher: IJSDR | www.ijsdr.org ISSN Number: 2455-2631 |
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