1,3-Dichloro-5,5-Dimethylhydantoin mediated oxidation of unsaturated alcohols in aqueous acetic acid medium

Divakar Prasad Sharma , Saras Tiwari

1,3-dichloro-5,5-dimethylhydantoin, α-crotonic acid, cinnamic acid, oxidation, kinetics.

In this perspective, the use of redox process are addressed in kinetic study of unsaturated alcohols (α-crotyl and cinnamyl alcohols) by DCDMH. Kinetic evidence for the formation of a DCDMH– unsaturated alcohol 1:1 complex has been assigned. The rate-limiting step involves the breaking of the α-C-H bond to afford corresponding aldehydes in good yields, and oxidizing ability of DCDMH species have been discussed. Mechanism with the associated reaction kinetics is assigned in accordance with the rate law and kinetic parameters.

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"1,3-Dichloro-5,5-Dimethylhydantoin mediated oxidation of unsaturated alcohols in aqueous acetic acid medium", IJSDR - International Journal of Scientific Development and Research (www.IJSDR.org), ISSN:2455-2631, Vol.8, Issue 7, page no.881 - 885, July-2023, Available :https://ijsdr.org/papers/IJSDR2307132.pdf

Volume 8 Issue 7, July-2023

Pages : 881 - 885

Paper Reg. ID: IJSDR_207906

Published Paper Id: IJSDR2307132

Downloads: 000347230

Research Area: Chemistry

Country: -, -, -

Published Paper PDF: https://ijsdr.org/papers/IJSDR2307132

Published Paper URL: https://ijsdr.org/viewpaperforall?paper=IJSDR2307132

ISSN: 2455-2631 | IMPACT FACTOR: 9.15 Calculated By Google Scholar | ESTD YEAR: 2016

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