INTERNATIONAL JOURNAL OF SCIENTIFIC DEVELOPMENT AND RESEARCH International Peer Reviewed & Refereed Journals, Open Access Journal ISSN Approved Journal No: 2455-2631 | Impact factor: 8.15 | ESTD Year: 2016
open access , Peer-reviewed, and Refereed Journals, Impact factor 8.15
Oxidation Kinetics of Some Cyclonols by N-bromosuccinimide in Aqueous Acetic Acid and Micellar medium
Authors Name:
Dheerendra Kumar Shukla
, Umesh Kumar Vishwakarma
Unique Id:
IJSDR2307131
Published In:
Volume 8 Issue 7, July-2023
Abstract:
The kinetic oxidation of cycloheptanol and cyclooctanol were described with an emphasis of correlation of structure and reactivity. The reaction were first-order with respect to loss of [NBS] N-bromosuccinimide and reaction are [H+] that follow kobs = a+b [H+]. However, Michaelis-Menten type kinetics were observed for the cyclonols. The micellar CTAB exhibited the existence of ternary complex behaviours between oxidant species and substrate at transition state. Based on kinetic data, thermodynamic parameters and reacting species HOBr of oxidant with 1:1 stoichiometry a mechanism was pastulated with the expulsion of α-H hydride anion.
"Oxidation Kinetics of Some Cyclonols by N-bromosuccinimide in Aqueous Acetic Acid and Micellar medium", International Journal of Science & Engineering Development Research (www.ijsdr.org), ISSN:2455-2631, Vol.8, Issue 7, page no.876 - 880, July-2023, Available :http://www.ijsdr.org/papers/IJSDR2307131.pdf
Downloads:
000338536
Publication Details:
Published Paper ID: IJSDR2307131
Registration ID:207892
Published In: Volume 8 Issue 7, July-2023
DOI (Digital Object Identifier):
Page No: 876 - 880
Publisher: IJSDR | www.ijsdr.org
ISSN Number: 2455-2631
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