INTERNATIONAL JOURNAL OF SCIENTIFIC DEVELOPMENT AND RESEARCH International Peer Reviewed & Refereed Journals, Open Access Journal ISSN Approved Journal No: 2455-2631 | Impact factor: 8.15 | ESTD Year: 2016
open access , Peer-reviewed, and Refereed Journals, Impact factor 8.15
Kinetics of Oxidation of Aldehyde by Piperidinium Chlorochromate
Authors Name:
Sandeep Kumar Chaurasia
, Saras Tiwari
Unique Id:
IJSDR2307129
Published In:
Volume 8 Issue 7, July-2023
Abstract:
Oxidation of aliphatic aldehydes (acetaldehyde and propanaldehyde) by piperidinium chlorochromate (Pipcc.) in aqueous acetic acid medium proceeds a mechanism involving transfer of hydride ion from aldehyde to pipcc. (oxidant) through an intermediate complex. The reaction is sensitized by hydrogen ions. The oxidation of aldehydes indicated an α-C-H bond cleavage in the rate-determining step leads to formation of corresponding carboxylic acids. The reaction is first-order in Pipcc. The structure-reactivity correlation with thermodynamic parameters and non-kinetic parameters was suggested.
"Kinetics of Oxidation of Aldehyde by Piperidinium Chlorochromate", International Journal of Science & Engineering Development Research (www.ijsdr.org), ISSN:2455-2631, Vol.8, Issue 7, page no.867 - 871, July-2023, Available :http://www.ijsdr.org/papers/IJSDR2307129.pdf
Downloads:
000338536
Publication Details:
Published Paper ID: IJSDR2307129
Registration ID:207890
Published In: Volume 8 Issue 7, July-2023
DOI (Digital Object Identifier):
Page No: 867 - 871
Publisher: IJSDR | www.ijsdr.org
ISSN Number: 2455-2631
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