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Kinetics and Mechanism of Phosphotungustic acid Catalysed Oxidation of 2-hexanone by N-bromoisonicotinamide in Aqueous Acetic acid
Authors Name:
Shahina Khan
, K. N. Sharma
Unique Id:
IJSDR2305075
Published In:
Volume 8 Issue 5, May-2023
Abstract:
The temperature dependence and catalysed rate coefficients for the reactions between 2-hexanone and N-bromoisonicotinamide have been determined. The stoichiometry correspondence to reaction in which one mole of enolic hexanone reacts with 2 moles of N-bromoisonicotinamide was assigned. The reaction shows the Michalis- Menten type of kinetics at the transition state which decomposes to form dione. A plausible reaction mechanism with derived rate law accounts for all experimental observations has been proposed. Various kinetic and activation parameters have been measured.
"Kinetics and Mechanism of Phosphotungustic acid Catalysed Oxidation of 2-hexanone by N-bromoisonicotinamide in Aqueous Acetic acid", International Journal of Science & Engineering Development Research (www.ijsdr.org), ISSN:2455-2631, Vol.8, Issue 5, page no.535 - 540, May-2023, Available :http://www.ijsdr.org/papers/IJSDR2305075.pdf
Downloads:
000222061
Publication Details:
Published Paper ID: IJSDR2305075
Registration ID:205391
Published In: Volume 8 Issue 5, May-2023
DOI (Digital Object Identifier):
Page No: 535 - 540
Publisher: IJSDR | www.ijsdr.org
ISSN Number: 2455-2631
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