INTERNATIONAL JOURNAL OF SCIENTIFIC DEVELOPMENT AND RESEARCH International Peer Reviewed & Refereed Journals, Open Access Journal ISSN Approved Journal No: 2455-2631 | Impact factor: 8.15 | ESTD Year: 2016
open access , Peer-reviewed, and Refereed Journals, Impact factor 8.15
Mechanism of α-Crotonic Acid towards N-Chlorosaccharin Oxidation
Authors Name:
Ranjana Singh
, Vinod Dubey
Unique Id:
IJSDR2301164
Published In:
Volume 8 Issue 1, January-2023
Abstract:
The oxidative study of α-crotonic acid in aqueous acetic acid by N-chlorosaccharin resulted in the formation of hydroxy aldehyde. The mechanism involving α-C-H fission from substrate to oxidant via an intermediate complex in rate determining step is discussed. The effect of dielectric constant of the medium indicates the rection to be of ion-dipole type. The reaction is first-order in [NCSA] and fractional-order to [H+]. Various kinetic and thermodynamic parameters were determined.
"Mechanism of α-Crotonic Acid towards N-Chlorosaccharin Oxidation", International Journal of Science & Engineering Development Research (www.ijsdr.org), ISSN:2455-2631, Vol.8, Issue 1, page no.1036 - 1039, January-2023, Available :http://www.ijsdr.org/papers/IJSDR2301164.pdf
Downloads:
000337072
Publication Details:
Published Paper ID: IJSDR2301164
Registration ID:203747
Published In: Volume 8 Issue 1, January-2023
DOI (Digital Object Identifier):
Page No: 1036 - 1039
Publisher: IJSDR | www.ijsdr.org
ISSN Number: 2455-2631
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