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INTERNATIONAL JOURNAL OF SCIENTIFIC DEVELOPMENT AND RESEARCH International Peer Reviewed & Refereed Journals, Open Access Journal ISSN Approved Journal No: 2455-2631 | Impact factor: 8.15 | ESTD Year: 2016 open access , Peer-reviewed, and Refereed Journals, Impact factor 8.15 |
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| Paper Title: | Kinetic and Viscometric studies of oxidation of Sucrose and Fructose by Vanadium (V) in Sulphuric acid medium |
| Authors Name: | BHUWAN CHANDRA , DEEPESH KUMAR TAMTA , NAVEEN CHANDRA , NARAIN DUTT KANDPAL |
| Unique Id: | IJSDR2211187 |
| Published In: | Volume 7 Issue 11, November-2022 |
| Abstract: | Investigations were carried out on the oxidation of fructose and sucrose by Vanadium (V) in aqueous sulphuric acid at temperature 298 K.The kobs increases linearly with concentration of both the sugars. The effect of viscosity of the aqueous sulphuric acid on rate constant has also been investigated to make a study of viscosity of the medium on the rate of oxidation. In case of both the substrates the rate of oxidation follow the linear relationship with the viscosity of the reaction medium with linearity coefficient greater than 0.98.The reaction was first order with respect to substrates and accelerated with the increase in the sulphuric acid concentration. The proposed mechanism of the oxidation based on the formation of the vanadium (V) complex ion leads to the formation of free radical of the substrates. |
| Keywords: | Redox reactions, Sugars, Vanadium (V), Complex ion, Viscosity, Sulphuric acid |
| Cite Article: | "Kinetic and Viscometric studies of oxidation of Sucrose and Fructose by Vanadium (V) in Sulphuric acid medium ", International Journal of Science & Engineering Development Research (www.ijsdr.org), ISSN:2455-2631, Vol.7, Issue 11, page no.1243 - 1250, November-2022, Available :http://www.ijsdr.org/papers/IJSDR2211187.pdf |
| Downloads: | 000337068 |
| Publication Details: | Published Paper ID: IJSDR2211187 Registration ID:202783 Published In: Volume 7 Issue 11, November-2022 DOI (Digital Object Identifier): Page No: 1243 - 1250 Publisher: IJSDR | www.ijsdr.org ISSN Number: 2455-2631 |
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